Skip to main content
Geosciences LibreTexts

16.41: Iolite

  • Page ID
    4725
  • \( \newcommand{\vecs}[1]{\overset { \scriptstyle \rightharpoonup} {\mathbf{#1}} } \)

    \( \newcommand{\vecd}[1]{\overset{-\!-\!\rightharpoonup}{\vphantom{a}\smash {#1}}} \)

    \( \newcommand{\id}{\mathrm{id}}\) \( \newcommand{\Span}{\mathrm{span}}\)

    ( \newcommand{\kernel}{\mathrm{null}\,}\) \( \newcommand{\range}{\mathrm{range}\,}\)

    \( \newcommand{\RealPart}{\mathrm{Re}}\) \( \newcommand{\ImaginaryPart}{\mathrm{Im}}\)

    \( \newcommand{\Argument}{\mathrm{Arg}}\) \( \newcommand{\norm}[1]{\| #1 \|}\)

    \( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\)

    \( \newcommand{\Span}{\mathrm{span}}\)

    \( \newcommand{\id}{\mathrm{id}}\)

    \( \newcommand{\Span}{\mathrm{span}}\)

    \( \newcommand{\kernel}{\mathrm{null}\,}\)

    \( \newcommand{\range}{\mathrm{range}\,}\)

    \( \newcommand{\RealPart}{\mathrm{Re}}\)

    \( \newcommand{\ImaginaryPart}{\mathrm{Im}}\)

    \( \newcommand{\Argument}{\mathrm{Arg}}\)

    \( \newcommand{\norm}[1]{\| #1 \|}\)

    \( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\)

    \( \newcommand{\Span}{\mathrm{span}}\) \( \newcommand{\AA}{\unicode[.8,0]{x212B}}\)

    \( \newcommand{\vectorA}[1]{\vec{#1}}      % arrow\)

    \( \newcommand{\vectorAt}[1]{\vec{\text{#1}}}      % arrow\)

    \( \newcommand{\vectorB}[1]{\overset { \scriptstyle \rightharpoonup} {\mathbf{#1}} } \)

    \( \newcommand{\vectorC}[1]{\textbf{#1}} \)

    \( \newcommand{\vectorD}[1]{\overrightarrow{#1}} \)

    \( \newcommand{\vectorDt}[1]{\overrightarrow{\text{#1}}} \)

    \( \newcommand{\vectE}[1]{\overset{-\!-\!\rightharpoonup}{\vphantom{a}\smash{\mathbf {#1}}}} \)

    \( \newcommand{\vecs}[1]{\overset { \scriptstyle \rightharpoonup} {\mathbf{#1}} } \)

    \( \newcommand{\vecd}[1]{\overset{-\!-\!\rightharpoonup}{\vphantom{a}\smash {#1}}} \)

    \(\newcommand{\avec}{\mathbf a}\) \(\newcommand{\bvec}{\mathbf b}\) \(\newcommand{\cvec}{\mathbf c}\) \(\newcommand{\dvec}{\mathbf d}\) \(\newcommand{\dtil}{\widetilde{\mathbf d}}\) \(\newcommand{\evec}{\mathbf e}\) \(\newcommand{\fvec}{\mathbf f}\) \(\newcommand{\nvec}{\mathbf n}\) \(\newcommand{\pvec}{\mathbf p}\) \(\newcommand{\qvec}{\mathbf q}\) \(\newcommand{\svec}{\mathbf s}\) \(\newcommand{\tvec}{\mathbf t}\) \(\newcommand{\uvec}{\mathbf u}\) \(\newcommand{\vvec}{\mathbf v}\) \(\newcommand{\wvec}{\mathbf w}\) \(\newcommand{\xvec}{\mathbf x}\) \(\newcommand{\yvec}{\mathbf y}\) \(\newcommand{\zvec}{\mathbf z}\) \(\newcommand{\rvec}{\mathbf r}\) \(\newcommand{\mvec}{\mathbf m}\) \(\newcommand{\zerovec}{\mathbf 0}\) \(\newcommand{\onevec}{\mathbf 1}\) \(\newcommand{\real}{\mathbb R}\) \(\newcommand{\twovec}[2]{\left[\begin{array}{r}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\ctwovec}[2]{\left[\begin{array}{c}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\threevec}[3]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\cthreevec}[3]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\fourvec}[4]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\cfourvec}[4]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\fivevec}[5]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\cfivevec}[5]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\mattwo}[4]{\left[\begin{array}{rr}#1 \amp #2 \\ #3 \amp #4 \\ \end{array}\right]}\) \(\newcommand{\laspan}[1]{\text{Span}\{#1\}}\) \(\newcommand{\bcal}{\cal B}\) \(\newcommand{\ccal}{\cal C}\) \(\newcommand{\scal}{\cal S}\) \(\newcommand{\wcal}{\cal W}\) \(\newcommand{\ecal}{\cal E}\) \(\newcommand{\coords}[2]{\left\{#1\right\}_{#2}}\) \(\newcommand{\gray}[1]{\color{gray}{#1}}\) \(\newcommand{\lgray}[1]{\color{lightgray}{#1}}\) \(\newcommand{\rank}{\operatorname{rank}}\) \(\newcommand{\row}{\text{Row}}\) \(\newcommand{\col}{\text{Col}}\) \(\renewcommand{\row}{\text{Row}}\) \(\newcommand{\nul}{\text{Nul}}\) \(\newcommand{\var}{\text{Var}}\) \(\newcommand{\corr}{\text{corr}}\) \(\newcommand{\len}[1]{\left|#1\right|}\) \(\newcommand{\bbar}{\overline{\bvec}}\) \(\newcommand{\bhat}{\widehat{\bvec}}\) \(\newcommand{\bperp}{\bvec^\perp}\) \(\newcommand{\xhat}{\widehat{\xvec}}\) \(\newcommand{\vhat}{\widehat{\vvec}}\) \(\newcommand{\uhat}{\widehat{\uvec}}\) \(\newcommand{\what}{\widehat{\wvec}}\) \(\newcommand{\Sighat}{\widehat{\Sigma}}\) \(\newcommand{\lt}{<}\) \(\newcommand{\gt}{>}\) \(\newcommand{\amp}{&}\) \(\definecolor{fillinmathshade}{gray}{0.9}\)
    Iolite
    Chemical composition Complex Mg-Al (magnesium aluminum) silicate
    Crystal system Orthorhombic
    Habit Massive, prisms
    Cleavage Distinct, basal
    Fracture Sub-conchoidal
    Hardness 7.5
    Optic nature Biaxial -
    Refractive index 1.53 - 1.55
    Birefringence 0.008 - 0.012
    Dispersion Low, 0.017
    Specific gravity 2.58 - 2.74
    Lustre Vitreous
    Pleochroism Strongly trichroic

    Figure \(\PageIndex{1}\): Marquise Shaped Faceted Iolite, courtesy of Richard Kocerek.

    Iolite is also named "water sapphire", cordierite or dichroite. Iolite has been worn for centuries and derives its name from “Ios” - the Greek word for violet. It is often claimed, that due to its strong pleochroism, ancient Vikings used iolite for navigation on cloudy days. It is conjectured that the gemstone acted as a polarizing filter and allowed the ancient sailors to determine the position of the sun. Although this is a widely published story, there is no empirical archaeological evidence that actually supports it.
    The soft blue color makes it a very attractive gemstone. Iolite is the 21st anniversary gemstone.

    Iolite is a color variety of the mineral cordierite. Sometimes the name "cordierite" is used to indicate "iolite".
    The green variety of cordierite is named praseolite.

    Diagnostics

    Iolite may be confused (due to its color) with sapphire and tanzanite.

    Color

    Iolite is usually blue to violetish-blue. Rarely it is colorless.

    Magnification

    Iolite is a type II stone in the GIA clarity grading system is usually included. Typical inclusions are:

    • liquid feathers
    • hexagonal platelets of biotite, hematite or pyrrothite

    File:Iolite inclusions1.jpg

    Figure \(\PageIndex{2}\): Hexagonal platelets, liquid feathers
    60X Magnification
    By Barbra Voltaire



    The iolite pictured above features liquid feathers, internal cleavage planes, and randomly oriented hexagonal platelets, possibly biotite or pyrrothite.

    Optical and physical properties

    Although iolite is usually confused with sapphire and tanzanite due to its color, its optical properties will distinguish iolite from them easily.

    Pleochroism

    Iolite is very strongly trichroic and this is the primary test in separating iolite from other gemstones. The three colors you will find are through dichroscopic examination are:

    1. violet-blue
    2. pale-blue
    3. pale yellow

    Sapphire is dichroic and although unheated tanzanite is also trichroic like iolite, the heated tanzanite is dichroic. Natural unheated tanzanite is very rare.

    Refractometer

    Iolite is biaxial with a negative optic sign. The β ray is almost halfway between α and γ so precise readings should be taken.
    A typical reading will be nα = 1.535-1.539 and nγ = 1.540-1.543
    The maximum birefringence ranges from 0.008 to 0.012
    Tanzanite is also biaxial but has a positive optic sign and its values are too high to indicate iolite. Sapphire is uniaxial and the readings are also too high.

    Quartz has RI readings in the range of iolite, but is uniaxial.


    This page titled 16.41: Iolite is shared under a CC BY-NC-SA 2.5 license and was authored, remixed, and/or curated by gemology via source content that was edited to the style and standards of the LibreTexts platform.

    • Was this article helpful?