There are numerous types of fossil fuels, but all of them involve the storage of organic matter in sediments or sedimentary rocks. Fossil fuels are rich in carbon and almost all of that carbon ultimately originates from CO2 taken out of the atmosphere during photosynthesis. That process, driven by solar energy, involves reduction (the opposite of oxidation) of the carbon, resulting in it being combined with hydrogen instead of oxygen. The resulting organic matter is made up of complex and varied carbohydrate molecules.
Most organic matter is oxidized back to CO2 relatively quickly (within weeks or years in most cases), but any of it that gets isolated from the oxygen of the atmosphere (for example, deep in the ocean or in a stagnant bog) may last long enough to be buried by sediments and, if so, may be preserved for tens to hundreds of millions of years. Under natural conditions, that means it will be stored until those rocks are eventually exposed at the surface and weathered.
In this section, we’ll discuss the origins and extraction of the important fossils fuels, including coal, oil, and gas. Coal, the first fossil fuel to be widely used, forms mostly on land in swampy areas adjacent to rivers and deltas in areas with humid tropical to temperate climates. The vigorous growth of vegetation leads to an abundance of organic matter that accumulates within stagnant water, and thus does not decay and oxidize. This situation, where the dead organic matter is submerged in oxygen-poor water, must be maintained for centuries to millennia in order for enough material to accumulate to form a thick layer (Figure 20.3.1a). At some point, the swamp deposit is covered with more sediment — typically because a river changes its course or sea level rises (Figure 20.3.1b). As more sediments are added, the organic matter starts to become compressed and heated. Low-grade lignite coal forms at depths between a few 100 m and 1,500 m and temperatures up to about 50°C (Figure 20.3.1c). At between 1,000 m to 5,000 m depth and temperatures up to 150°C m, bituminous coal forms (Figure 20.3.1d). At depths beyond 5,000 m and temperatures over 150°C, anthracite coal forms.
While almost all coal forms on land from terrestrial vegetation, most oil and gas is derived primarily from marine micro-organisms that accumulate within sea-floor sediments. In areas where marine productivity is high, dead organic matter is delivered to the sea floor fast enough that some of it escapes oxidation. This material accumulates in the muddy sediments, which become buried to significant depth beneath other sediments.
As the depth of burial increases, so does the temperature — due to the geothermal gradient — and gradually the organic matter within the sediments is converted to hydrocarbons (Figure 20.3.3). The first stage is the biological production (involving anaerobic bacteria) of methane. Most of this escapes back to the surface, but some is trapped in methane hydrates near the sea floor. At depths beyond about 2 km, and at temperatures ranging from 60° to 120°C, the organic matter is converted by chemical processes to oil. This depth and temperature range is known as the oil window. Beyond 120°C most of the organic matter is chemically converted to methane.
Exercise 20.4 Interpreting a Seismic Profile
The cross-section shown here is from a ship-borne seismic survey in the Bering Sea off the west coast of Alaska. As a petroleum geologist, it’s your job to pick two separate locations to drill for oil or gas. Which locations would you choose?
[from USGS at: http://walrus.wr.usgs.gov/infobank/p...ion/seis.html]
The type of oil and gas reservoirs illustrated in Figures 20.3.4 and 20.3.5 are described as conventional reserves. Some unconventional types of oil and gas include oil sands, shale gas, and coal-bed methane.
Oil sands are important because the reserves in Alberta are so large (the largest single reserve of oil in the world), but they are very controversial from an environmental and social perspective. They are “unconventional” because the oil is exposed near the surface and is highly viscous because of microbial changes that have taken place at the surface. The hydrocarbons that form this reserve originated in deeply buried Paleozoic rocks adjacent to the Rocky Mountains and migrated up and toward the east (Figure 20.3.6).
The oil sands are controversial primarily because of the environmental cost of their extraction. Since the oil is so viscous, it requires heat to make it sufficiently liquid to process. This energy comes from gas; approximately 25 m3 of gas is used to produce 0.16 m3 (one barrel) of oil. (That’s not quite as bad as it sounds, as the energy equivalent of the required gas is about 20% of the energy embodied in the produced oil.) The other environmental cost of oil sands production is the devastation of vast areas of land where strip-mining is taking place and tailings ponds are constructed, and the unavoidable release of contaminants into the groundwater and rivers of the region.
At present, most oil recovery from oil sands is achieved by mining the sand and processing it on site. Exploitation of oil sand that is not exposed at the surface depends on in situ processes, an example being the injection of steam into the oil-sand layer to reduce the viscosity of the oil so that it can be pumped to the surface.
Shale gas is gas that is trapped within rock that is too impermeable for the gas to escape under normal conditions, and it can only be extracted by fracturing the reservoir rock using water and chemicals under extremely high pressure. This procedure is known as hydraulic fracturing or “fracking.” Fracking is controversial because of the volume of water used, and because, in some jurisdictions, the fracking companies are not required to disclose the nature of the chemicals used. Although fracking is typically done at significant depths, there is always the risk that overlying water-supply aquifers could be contaminated (Figure 20.3.7). Fracking also induces low-level seismicity.
During the process that converts organic matter to coal, some methane is produced, which is stored within the pores of the coal. When coal is mined, methane is released into the mine where it can become a serious explosion hazard. Modern coal-mining machines have methane detectors on them and actually stop operating if the methane levels are dangerous. It is possible to extract the methane from coal beds without mining the coal; gas recovered this way is known as coal-bed methane.