8.3: Management of Nitrogen and Phosphorus
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\(\newcommand{\avec}{\mathbf a}\) \(\newcommand{\bvec}{\mathbf b}\) \(\newcommand{\cvec}{\mathbf c}\) \(\newcommand{\dvec}{\mathbf d}\) \(\newcommand{\dtil}{\widetilde{\mathbf d}}\) \(\newcommand{\evec}{\mathbf e}\) \(\newcommand{\fvec}{\mathbf f}\) \(\newcommand{\nvec}{\mathbf n}\) \(\newcommand{\pvec}{\mathbf p}\) \(\newcommand{\qvec}{\mathbf q}\) \(\newcommand{\svec}{\mathbf s}\) \(\newcommand{\tvec}{\mathbf t}\) \(\newcommand{\uvec}{\mathbf u}\) \(\newcommand{\vvec}{\mathbf v}\) \(\newcommand{\wvec}{\mathbf w}\) \(\newcommand{\xvec}{\mathbf x}\) \(\newcommand{\yvec}{\mathbf y}\) \(\newcommand{\zvec}{\mathbf z}\) \(\newcommand{\rvec}{\mathbf r}\) \(\newcommand{\mvec}{\mathbf m}\) \(\newcommand{\zerovec}{\mathbf 0}\) \(\newcommand{\onevec}{\mathbf 1}\) \(\newcommand{\real}{\mathbb R}\) \(\newcommand{\twovec}[2]{\left[\begin{array}{r}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\ctwovec}[2]{\left[\begin{array}{c}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\threevec}[3]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\cthreevec}[3]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\fourvec}[4]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\cfourvec}[4]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\fivevec}[5]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\cfivevec}[5]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\mattwo}[4]{\left[\begin{array}{rr}#1 \amp #2 \\ #3 \amp #4 \\ \end{array}\right]}\) \(\newcommand{\laspan}[1]{\text{Span}\{#1\}}\) \(\newcommand{\bcal}{\cal B}\) \(\newcommand{\ccal}{\cal C}\) \(\newcommand{\scal}{\cal S}\) \(\newcommand{\wcal}{\cal W}\) \(\newcommand{\ecal}{\cal E}\) \(\newcommand{\coords}[2]{\left\{#1\right\}_{#2}}\) \(\newcommand{\gray}[1]{\color{gray}{#1}}\) \(\newcommand{\lgray}[1]{\color{lightgray}{#1}}\) \(\newcommand{\rank}{\operatorname{rank}}\) \(\newcommand{\row}{\text{Row}}\) \(\newcommand{\col}{\text{Col}}\) \(\renewcommand{\row}{\text{Row}}\) \(\newcommand{\nul}{\text{Nul}}\) \(\newcommand{\var}{\text{Var}}\) \(\newcommand{\corr}{\text{corr}}\) \(\newcommand{\len}[1]{\left|#1\right|}\) \(\newcommand{\bbar}{\overline{\bvec}}\) \(\newcommand{\bhat}{\widehat{\bvec}}\) \(\newcommand{\bperp}{\bvec^\perp}\) \(\newcommand{\xhat}{\widehat{\xvec}}\) \(\newcommand{\vhat}{\widehat{\vvec}}\) \(\newcommand{\uhat}{\widehat{\uvec}}\) \(\newcommand{\what}{\widehat{\wvec}}\) \(\newcommand{\Sighat}{\widehat{\Sigma}}\) \(\newcommand{\lt}{<}\) \(\newcommand{\gt}{>}\) \(\newcommand{\amp}{&}\) \(\definecolor{fillinmathshade}{gray}{0.9}\)Nitrogen and phosphorus behave very differently in soils, but many of the management strategies are actually the same or very similar. They include the following:
- Take all nutrient sources into account.
- Estimate nutrient availability from all sources.
- Use soil tests to assess available nutrients. (Nitrogen soil tests are not available for all states. Some make N fertilizer recommendations based on fertilizer trials and estimates of cover crop contributions. Other methods for making N recommendations are discussed later in this chapter.)
- Use manure and compost tests to determine nutrient contributions.
- Consider nutrients in decomposing crop residues (for N only).
- Reduce losses and enhance uptake (use 4R-Plus principles, fertilizer application using the right rate, at the right time, in the right place, in the right amount, plus conservation practices).
- Use nutrient sources more efficiently.
- Use localized placement of fertilizers below the soil surface whenever possible.
- Split fertilizer application if leaching or denitrification losses are a potential problem (almost always for N only).
- Apply nutrients when leaching or runoff threats are minimal.
- Reduce tillage.
- Use cover crops.
- Include perennial forage crops in rotation.
- Balance farm imports and exports once crop needs are being met.
Cover crops combined with minimal or no tillage is a set of practices that work well together. They improve soil structure; reduce the loss of nutrients through leaching, runoff, and erosion; reduce denitrification loss of nitrates; and tie up N and P that otherwise might be lost between cash crops by storing these nutrients in organic forms.
Estimating Nutrient Availability

Good N and P management practices take into account the large amount of plant-available nutrients that come from the soil, especially soil organic matter and any additional organic sources like manure, compost, or a rotation crop or cover crop. Fertilizers should be used only to supplement the soil’s supply in order to provide full plant nutrition. Organic farmers try to meet all demands through these soil sources because additional organic fertilizers are generally very expensive. This is typically done by incorporating a legume as a crop or cover crop into the rotation or by adding high-N organic nutrient sources. When using organic fertilizers, the higher the percent N in the compost or in the other material, the more N will become available to plants. Little to no N will be available to plants if the amendment is around 2% N or less (corresponding to a high C:N ratio). But if it’s around 5% N, about 40% of the N in the amendment will be available. And if it’s 10% or 15% N (corresponding to a very low C:N ratio), 70 percent or more of the N in the amendment will be available to crops. On integrated crop-livestock farms soil organic N and P sources are typically sufficient to meet the crop’s demand, but not always.
Since most plant-available P in soils is relatively strongly adsorbed by organic matter and clay minerals, estimating P availability is routinely done through soil tests. The amount of P extracted by chemical soil solutions can be compared with results from crop response experiments and can provide good estimates of the likelihood of a response to P fertilizer additions.

Estimating N fertilizer needs is more complex, and soil tests generally cannot provide all the answers. The primary reason is that the amounts of plant-available N, mostly nitrate, can fluctuate rapidly as organic matter is mineralized and as N is lost through leaching or denitrification. These processes are greatly dependent on soil organic matter contents, additional N contributions from organic amendments, weather-related factors like soil temperature (higher temperatures increase N mineralization), and soil wetness (saturated soils cause large leaching and denitrification losses, especially when soils are warm). Mineral forms of N begin to accumulate in soil in the spring but may be lost by leaching and denitrification during a very wet period. When plants germinate in the spring, it takes a while until they begin to grow rapidly and take up a lot of N. Weather affects the required amount of supplemental N in two primary ways. In years with unusually wet weather in the spring, an extra amount of sidedress (or topdress) N may be needed to compensate for relatively high mineral N loss from soil. The increasing rainfall intensity in some regions makes the use of sidedress N even more important. Research on corn in Minnesota from 2015 to 2019—where 75 percent of the sites evaluated had one month during the growing season with 150 percent of normal rainfall—indicated using sidedress N with some N applied before planting didn't decrease yields and actually increased yields by an average of 11 bushels an acre in a quarter of situations.
On the other hand, in dry years, especially drought spells during the critical pollination period, yields will be reduced, and the N uptake and needed N fertilizer are therefore lower. However, you really don’t know at normal sidedress time whether there will be a drought during pollination, so there is no way to adjust for that. For a field with a given soil type and set of management practices, the actual amount of required N also depends on the complex and dynamic interplay of crop growth patterns with weather events, which are difficult to predict. In fact, optimum N fertilizer rates for corn without organic amendments in the U.S. corn belt have been found to vary from as little as 0 pounds per acre to as much as 250 pounds per acre. Those are the extremes, but, nevertheless, it is a great challenge to determine the optimum economic N rate. There may be different issues arising in other regions. In the Northwest’s maritime region, large amounts of winter rainfall normally result in very low levels of available N in spring. Without much year-to-year carryover of mineral N and with low organic matter decomposition during the cool season, it is especially important to be sure that some readily available N is near the developing seedling of spring planted crops.
Fixed and Adaptive Methods for Estimating Crop N Needs
Several approaches are used to estimate crop N needs, and they can be grouped into fixed and adaptive approaches. Fixed (static) approaches assume that the N fertilizer needs do not vary from one season to another based on weather conditions, which may work well in drier climates but are very imprecise in a humid climate. Adaptive methods recognize that precise N fertilization requires additional data from field samples, sensors or computer models to modify the N rate for a particular production environment.
The mass-balance approach, a fixed approach, is the most commonly used method for estimating N fertilizer recommendations. It is generally based on a yield goal and associated N uptake, minus credits given for non-fertilizer N sources such as mineralized N from soil organic matter, preceding crops, and organic amendments. However, studies have shown that the relationship between yield and optimum N rate is very weak for humid regions. While higher yields do require more N, the weather pattern that produces higher yields also implies 1) that larger and healthier root systems can take up more soil N, and 2) that frequently the weather pattern stimulates the presence of higher levels of nitrate in the soil. Conversely, very wet conditions cause reduced yields due to insufficient soil aeration and low soil N availability.
Several leading U.S. corn-producing states have adopted the maximum return to N (MRTN) approach, another fixed method that largely abandons the mass-balance approach. It provides generalized recommendations based on extensive field trials, model-fitting and economic analyses. It is only available for corn at this time. The rate with the largest average net return to the farmer over multiple years is the MRTN, and the recommendations vary with grain and fertilizer prices. Adjustments based on realistic yield expectations are sometimes encouraged. The MRTN recommendations are based on comprehensive field information, but owing to generalizing over large areas and over many seasons, it does not account for the soil and weather factors that affect N availability and is therefore inherently imprecise for an individual field.
The adaptive approaches, described in the following paragraphs, attempt to take into account seasonal weather, soil type, and management effects and require some type of measurement or model estimate during the growing season.
The pre-sidedress nitrate test (PSNT) measures soil nitrate content in the surface layer of 0–12 inches and allows for adaptive sidedress or topdress N applications. It implicitly incorporates information on early season weather conditions and is especially successful in identifying N-sufficient sites: those that do not need additional N fertilizer. It requires a special sampling effort during a short time window in late spring, and it is sensitive to timing and mineralization rates during the early spring. The PSNT is usually called the late spring nitrate test (LSNT) in the midwestern United States.
Pre-plant nitrate and labile N tests measure soil nitrate, soil nitrate plus ammonium, or readily available organic nitrogen in the soil early in the season to guide N fertilizer applications at planting. These approaches are more effective in drier climates, like in the U.S. Great Plains where seasonal gains of inorganic forms of N are more predictable and losses from leaching or denitrification are generally minimal. Fall soil sampling can provide valuable information for N management for winter wheat while early spring season sampling is preferable for evaluating N needs for corn. These approaches cannot incorporate the seasonal weather effects, as the samples are analyzed prior to the growing season, which inherently limits its precision compared to the PSNT. Recent advances in crop sensing and modeling allow adaptive approaches based on seasonal weather and local soil variation. Leaf chlorophyll meters that measure light transmission in leaves and satellite, aerial, drone, or tractor-mounted sensors that determine light reflection from leaves are used for assessing leaf or canopy N status and biomass, which can then guide sidedress N applications. Environmental information systems and dynamic simulation models are now also being employed for N management, with successful applications for wheat and corn. This approach takes advantage of increasingly sophisticated environmental databases, such as radar-based, high-resolution precipitation estimates, and detailed soil databases, and can be used to provide input information for computer models.
Evaluation at the End of the Season
To evaluate the success of a fertility recommendation, farmers sometimes plant field strips with different N rates and compare yields at the end of the season. This can be done for vegetable crops as well as for crops like grain corn. Another option is to sample for soil nitrate after harvest, sometimes called a “report card” assessment, to evaluate residual levels of available N. The lower stalk nitrate test is also sometimes used to assess, after the growing season, whether corn N rates were approximately right too low or too high. These methods are neither fixed nor adaptive approaches for the current year since evaluation is made at the end of the season, but they may help farmers make changes to their fertilizer application rates in the following years. Adaptive management may therefore also include farmer-based experimentation and adjustment to local conditions.
Planning for N and P Management
Although N and P behave very differently in soils, the general approaches to their management are similar. The following considerations are important for planning management strategies for N and P.
Nitrogen | Phosphorus |
---|---|
Use fixed-rate approaches for planning purposes and adaptive approaches to achieve precision. | Test soil regularly (and follow recommendations). |
Test manures and credit their N contribution. | Test manures and credit their P contribution. |
Use legume forage crops in rotation and/or legume cover crops to fix N for following crops, and properly credit legume N contribution to following crops. | No equivalent practice is available (although cover crop and cash crop mycorrhizae help mobilize soil P already there, making it more available to plants). |
Time N applications as close to crop uptake as possible, and place to reduce runoff or gaseous losses. | Time and place P application to reduce runoff potential. |
Reduce tillage in order to leave residues on the surface and to decrease runoff and erosion. | Reduce tillage in order to leave residues on the surface, decrease runoff and erosion, and keep the mycorrhizal network intact. |
Use sod-type forage crops in rotation to reduce nitrate leaching and runoff, making N more available to the following crops. | Use sod-type forage crops in rotation to reduce the amount of runoff and erosion losses of P, making P more available to the following crop. |
Use grass cover crops, such as cereal rye, to capture soil nitrates left following the economic crop. | Use grass-cover crops, such as cereal rye, to protect soil against erosion. |
Make sure that excessive N is not coming onto the farm (biological N fixation plus fertilizers plus feeds). | After soil tests are in the optimal range, balance the farm’s P flow (don’t import much more onto the farm than is being exported). |

Credit nutrients in manures, rotation crops, decomposing sods, cover crops, and other organic residues. Before applying commercial fertilizers or other off-farm nutrient sources, you should properly credit the various on-farm sources of nutrients. In some cases, there is more than enough fertility in the on-farm sources to satisfy crop needs. If manure is applied before sampling soil, the contribution of much of the manure’s P and all its potassium will be reflected in the soil test. The pre-sidedress nitrate test can estimate the N contribution of the manure. The only way to really know the nutrient value of a particular manure is to have it tested for its fertilizer value before applying it to the soil; many soil test labs also analyze manures. (Although a manure analysis test is recommended and will provide the most accurate result, estimates can be made based on average manure values.)
Because significant ammonia N losses can occur in as little as one or two days after application, the way to derive the full N benefit from surface-applied manure (or urea for that matter) is to incorporate it as soon as possible. Much of the manure N made available to the crop is in the ammonium form, and losses occur as some are volatilized as ammonia gas when manures dry on the soil surface. A significant amount of the manure’s N may also be lost when application happens a long time before crop uptake occurs. Even if incorporated, about half of the N value of a fall manure application may be lost by the time it is needed by the crop in the following year.
When using some tillage, it makes sense to incorporate manure as soon after application as weather and competing work priorities allow. With no-till there are low-disturbance manure injectors that place liquid manure in the soil with minimal N loss.
Legumes, either as part of rotations or as cover crops, and well-managed grass sod crops can add N to the soil for use by the next crop (Table \(\PageIndex{2}\)). Nitrogen fertilizer decisions should take into account the amount of N contributed by manures, decomposing sods, and cover crops. If you correctly fill out the form that accompanies your soil sample, the recommendation you receive may take these sources into account. However, not all soil testing labs do that; most do not even ask whether you’ve used a cover crop. Also, some of the adaptive simulation models described above can incorporate such credits into recommendations, while also accounting for variable weather conditions.
Previous crop | N credits (pounds per acre) |
---|---|
Corn and most other crops | 0 |
Soybeans2 | 0–40 |
Grass (low level of management) | 40 |
Grass (intensively managed, using N fertilizer for maximum economic yield) | 70 |
2-year stand of red or white clover | 70 |
3-year alfalfa stand (20–60% legume) | 70 |
3-year alfalfa stand (>60% legume) | 120 |
Crimson clover | 110 |
Winter peas | 110 |
Hairy vetch cover crop (excellent growth) | 110 |
1Less credit should be given for sandy soils with high amounts of leaching potential. 2Some labs give 30 or 40 pounds of N credit for soybeans, while others give no N credit. Credits represent the amount of N that will be available to the crop (not the total amount contained in residue). Although the actual amount of N that will become available can be higher in dry years and lower in wet years (Figure 19.2), we still can’t accurately predict the growing season weather. When following cover crops, the stage of growth and the amount of growth will strongly influence the amount of N available to the following crop. |
Relying on legumes to supply N to the following crops. Nitrogen is the only nutrient of which you can “grow” your own supply. High-yielding legume cover crops, such as hairy vetch and crimson clover, can supply most, if not all, of the N needed by the following crop. Growing a legume as a forage crop (alfalfa, alfalfa/ grass, clover, clover/grass) in rotation also can provide much, if not all, of the N for row crops.
Cover crops mobilize and take up a significant amount of P through mycorrhizae and other organisms of the root microbiome. Later, as they decompose, this P becomes available for the following crops to use. While this is a very different mechanism than N fixation by legumes, it is another example of a crop together with microorganisms helping the following crop obtain particular nutrients.
Animals on the farm or on nearby farms? There are many possibilities for actually eliminating the need for N fertilizer if you have ruminant animals on your farm or on nearby farms for which you can grow forage crops (and perhaps use the manure on your farm). A forage legume, such as alfalfa, red clover, or white clover, or a grass-legume mix, can supply substantial N for the following crop. Frequently, nutrients are imported onto livestock-based farms as various feeds (usually grains and soybean meal mixes). This means that the manure from the animals will contain nutrients imported from off the farm, and this reduces the need to purchase fertilizers. When planting vegetable crops following a manure application, keep in mind the regulation that requires 120 days from application to harvest.
No animals? Although land constraints don’t usually allow it, some vegetable farmers grow a forage legume for one or more years as part of a rotation, even when they are not planning to sell the crop or feed it to animals. They do so to rest the soil and to enhance the soil’s physical and biological properties, and nutrient status. Also, some cover crops, such as hairy vetch—grown off-season in the fall and early spring—can provide sufficient N for some of the high-demanding summer annuals. It’s also possible to undersow sweet clover, planning for fall brassica crops the following year. (If tillage is used, it can be plowed under the next July to prepare for the fall crop.) Sunn hemp and cowpeas growing as cover crops in the Southeast during the summer months have been found to replace one-third to one-half of the N needed for fall broccoli.
Reducing N and P Losses
Manage N and P fertilizers more efficiently. You should have plenty of organic nutrients present if you’ve worked to build and maintain soil organic matter. These readily decomposable fragments provide N and P as they decompose, thereby reducing the amount of fertilizer that’s needed.
When applying commercial fertilizers and manures, the timing and method of application affect the efficiency of use by crops and the amount of loss from soils, especially in humid climates. In general, it is best to apply fertilizers close to the time they are needed by plants, which is especially important when it involves N. Losses of surface-applied fertilizer and manure nutrients are also frequently reduced by soil incorporation with tillage (even light incorporation can help a lot). Liquid N fertilizer, especially when dribble applied, penetrates the surface, better protecting it from possible gaseous loss. And no-tilled soils that have continual living roots by using cover crops tend to have vastly greater water infiltration and less runoff and gaseous losses.
If you’re growing a crop for which a reliable in-season adaptive method is available, like the PSNT, a sensor or a computer model, you can hold off applying most of the fertilizer until the crop indicates a need. At that point, apply N as a sidedress or topdress. However, if you know that your soil is probably very N deficient (for example, a sandy soil low in organic matter), you may need to band-apply higher-than-normal levels of starter N at planting or broadcast some N before planting to supply sufficient N nutrition until the soil test indicates whether there is a need for more N (applied as a sidedress or topdress). About 15–20 pounds of starter N per acre (in a band at planting) is highly recommended for crops in colder climates. Even more starter N is needed when some cover crops like cereal rye or triticale are allowed to grow near maturity. The large amount of biomass, with its high C:N ratio, will tie up mineral sources of soil N for some weeks following cover crop termination. When organic farmers use fishmeal or seed meals to supply N to crops, they should plan on it becoming available over the season, with little released in the first weeks of decomposition. On the other hand, N contained in feather meal may become available more rapidly.
In-season topdressing N on wheat and on some other annual cereal or oilseed crops is sometimes needed, especially when wet conditions cause significant losses of available soil N. It’s helpful if farmers put high-N strips within fields, in which they apply N at rates of 40–50 pounds per acre higher than in other areas. The length and width of the strips aren’t that important. The purpose of the strips is to see if you can tell the difference between the wheat in the high-N strip and the rest of the field. Top dressing N is recommended if the difference is very noticeable.
If the soil is very deficient in phosphorus, P fertilizers have traditionally been incorporated by tillage to raise the general level of the nutrient. Incorporation is not possible with no-till systems, and if the soil is very deficient, some P fertilizer should be incorporated before starting no-till. Nutrients accumulate near the surface of reduced tillage systems when fertilizers or manures are repeatedly surface applied. If P levels are good to start with, in later years small amounts of surface-applied P will work their way deeper into the soil surface. P can be band applied as a starter fertilizer at planting, or it can be injected, keeping it below the surface.
In soils with optimal P levels, some P fertilizer is still recommended, along with N application, for row crops in cool regions. (Potassium is also commonly recommended under these conditions.) Frequently, the soils are cold enough in the spring to slow down root development, P diffusion toward the root, and mineralization of P from organic matter, thereby reducing P availability to seedlings. No-tilled soils with plentiful surface residue will stay cool for a longer period in the spring, thereby decreasing both N and P availability. However, if cover crops are used together with no-till—a combination that provides many benefits—soils will dry and warm more rapidly, lessening the concern with early P deficiency in row crops. But for no-till without cover crops in cool climates, it is a good idea to use a small amount of starter P for the young crop—even if the soil is in the optimal P soil test range.
Use the right fertilizer products. Some of the N in surface-applied urea, the cheapest and most commonly used solid N fertilizer, is lost as a gas if it is not rapidly incorporated into the soil. If as little as a quarter inch of rain falls within a few days of surface urea application, N losses are usually less than 10%. However, losses may be 30% or more in some cases (a 50% loss may occur following surface application to a calcareous soil that is over pH 8). When urea is used for no-till systems, it can be placed below the surface or surface applied in the form of chemically stabilized urea, greatly reducing N loss. Stabilized urea is the most economical source when N fertilizer is broadcast as a topdress on grass, on cereals such as wheat, or on row crops. Solutions of urea and ammonium nitrate (UAN) are also used as a topdress or are dribbled on as a band. (Although once widely used, solid ammonium nitrate fertilizer is expensive and not always readily available due to concerns about explosivity. But like calcium ammonium nitrate [CAN], its N is generally not lost as a gas when left on the surface and therefore is a good product for topdressing.)
Anhydrous ammonia, the least expensive source of N fertilizer, causes large changes in soil pH in and around the injection band. The pH increases for a period of weeks, many organisms are killed, and organic matter is rendered more soluble. Eventually, the pH decreases, and the band is repopulated by soil organisms. However, significant N losses can occur when anhydrous is applied in soil that is too dry or too wet. In humid regions, even if stabilizers are used, anhydrous applied long before crop uptake significantly increases the amount of N that may be lost. For this reason, fall-applied anhydrous ammonia is a practical N source only in the more arid western portion of the Corn Belt, and only after the soil has cooled below 50 degrees F. However, fall application of anhydrous ammonia remains relatively common even in the more humid parts of the region due to price and logistical benefits, but this raises environmental concerns.
In some cases, nutrients are applied individually through separate fertilizer products, while multi-nutrient compounds (like monoammonium phosphate) or blended materials are used in other cases. When applying multiple nutrients at once, aim to use combinations that proportionally fit the nutritional needs of your crop, thereby reducing unnecessary applications and buildup of nutrients that are overapplied. Or otherwise use multi-nutrient fertilizer in combination with single-nutrient products to achieve the right proportions.
Use nitrogen efficiency enhancement products. Field nitrogen losses can be high depending on the soil, the practices used, and the conditions of the growing season, especially the weather. With urea-based nitrogen fertilizers and manure, ammonia losses into the atmosphere can be considerable if the material is left on the surface, especially when conditions following application are dry and soil pH is high. Several products on the market reduce ammonia losses by suppressing the activity of the urease enzyme. These urease inhibitors reduce the production of ammonia by naturally occurring soil enzymes, lessening N losses as well as concerns about air pollution and unwanted nitrogen deposition in nearby areas. Nitrification inhibitors are another type of product for use with N fertilizers. These suppress the conversion of ammonium to nitrate by naturally occurring soil microorganisms. Ammonium is strongly held by negative charges on soil particles (the cation exchange complex) and does not leach from soils, while the negatively charged nitrate ion can wash through the soil when a lot of rain occurs. This is especially a concern with sandy soils. Also, in finer-textured soils, nitrate can be lost during wet periods through denitrification and volatilization of N2 and N2O into the air. Of course, the leaching and gaseous losses are detrimental to farm profitability as well as to the environment. The role of the nitrification inhibitor is to maintain nitrogen in the ammonium form for longer periods, slowly making nitrate available as the growing crop develops, thereby increasing use efficiency. A third type of product, similar to nitrification inhibitors, focuses on controlled release by using a coating on fertilizer material that causes it to slowly dissolve and release the nitrogen fertilizer.
Urea is converted to ammonia (lost to the atmosphere or dissolved in water to form ammonium as a gas, or converted to nitrate).
Ammonia and ammonium are nitrified to nitrate (easily lost by leaching and/or denitrification).
The choice of enhanced efficiency products depends on the fertilization strategy. Urease inhibitors are appropriate when using urea-based fertilizers without incorporation. When applying ammonia/ammonium-based fertilizers well before crop uptake, consider adding a nitrification inhibitor or using coated materials. In some cases, a combination of products is appropriate. In general, the use of these products reduces N losses, but it depends on the production environment in a particular growing season. It may prevent yield losses in some years or allow reductions in overall N fertilizer rates by reducing the need for using higher levels of fertilizer as “insurance.”
Mode of action | Formulation and use | Common enhanced efficiency products1 |
---|---|---|
Urease inhibition | Additive for urea-based; manure | NBPT, MIC |
Nitrification inhibition | Additive for anhydrous ammonia, urea- and ammonium-based | Nitrapyrin, DCD, MIC |
Urease and nitrification inhibition | Stand-alone fertilizer product | Ammonium and calcium thiosulfates |
Controlled release | Stand-alone fertilizer product | Polymer-coated prilled nitrogen or other nutrients |
1This list is not comprehensive but includes the most widely used products. The inclusion or omission of a product in this list does not imply an endorsement by the authors or publisher. Source: Cantarella, H., R. Otto, J.R. Soares and A.G. de Brito Silva. 2018. Agronomic efficiency of NBPT as a urease inhibitor: A review. Journal Advanced Research 13: 19–27. |
Corn is a tropical plant that is more efficient at utilizing N than most other crops: it produces more additional yield for each extra pound of N absorbed by the plant. But corn production systems as a whole have low efficiency of fertilizer N, typically less than 50%. Environmental N losses (leaching, denitrification, and runoff) are much higher for corn than for crops such as soybeans and wheat, especially when compared to alfalfa and grasses. This can be attributed to different crop growth cycles, fertilizer rates, fertilizer application schedules, timing of crop water and N uptake, and rooting depths. Intensive corn production areas have therefore become the focus of policy debates that address environmental concerns like groundwater contamination and hypoxia zones in estuaries.
Nitrogen management for corn is still mostly done without recognizing how seasonal weather, particularly precipitation, can cause high N losses through leaching and denitrification. The PSNT was the first approach that addressed these dynamic processes and therefore provided inherently more precise N fertilizer recommendations and eliminated a lot of unnecessary N applications. Still, many farmers like to apply additional “insurance fertilizer” because they want to be certain of an adequate N supply in wet years. But they may actually need it in only, say, one out of four seasons. For those other years, excess N application creates high environmental losses.
New technologies are emerging in addition to the PSNT that allow us to more precisely manage N. Computer models and climate databases can be employed to adapt N recommendations by accounting for weather events and in-field soil variability. Also, crop reflectance of light, which is affected by the degree of N nutrition in the plant, can be measured using aerial and satellite images or tractor-mounted sensors, and can then be used to adjust sidedress N fertilizer rates, even for small zones in a field (precision management).
Use perennial forages (sod-forming crops) in rotations. As we’ve discussed a number of times, rotations that include a perennial forage crop help reduce runoff and erosion; improve beneficial aggregation; break harmful weed, insect, and nematode cycles; and build soil organic matter. Decreasing the emphasis on row crops in a rotation and including perennial forages also helps decrease leaching losses of nitrate. This happens for two main reasons:
- There is less water leaching under a sod because it uses more water over the entire growing season than does an annual row crop, which has bare soil in the spring and after harvest in the fall.
- Nitrate concentrations under sod rarely reach anywhere near as high as those under row crops.
So, whether the rotation includes a grass, a legume or a legume-grass mix, the amount of nitrate leaching to groundwater is usually reduced. (A critical step, however, is the conversion from sod to row crop. When a sod crop is plowed, a lot of N is mineralized. If this occurs many months before the row crop takes it up, high nitrate leaching and denitrification losses occur.) Using grass, legume or grass-legume forages in the rotation also helps with P management because of the reduced runoff and erosion, and the effects on soil structure for the following crop.
Use cover (catch) crops to prevent nutrient losses. High levels of soil nitrate may be left at the end of the growing season if drought causes a poor crop year or if excess N fertilizer or manure has been applied. The potential for nitrate leaching and runoff can be significantly reduced if you sow a fast-growing cover crop like cereal rye immediately after the main crop has been harvested. Such cover crops are commonly referred to as “catch crops” because their fast-growing roots can capture the remaining nutrients in the soil and store them in their biomass. One option available to help manage N is to use a combination of a legume and grass. The combination of hairy vetch and cereal rye or triticale works well in cooler temperate regions. When nitrate is scarce, the vetch or crimson clover does much better than the rye, and a large amount of N is fixed for the next crop. Conversely, the rye competes well with the vetch when nitrate is plentiful; less N is fixed (of course, less is needed); and much of the nitrate is tied up in the rye and stored for future use. Crimson clover with either cereal rye or oats works similarly in the South, with the clover growing better and fixing more N when soil nitrate is scarce, and with cereal rye growing faster when nitrate is plentiful.
In general, having any cover crop on the soil during the off-season is helpful for P management. A cover crop that establishes quickly and helps protect the soil against erosion will help reduce P losses.
Reduce tillage. Because most P is lost from fields by sediment erosion, environmentally sound P management should include reduced tillage systems. Leaving residues on the surface and maintaining stable soil aggregation and lots of large pores help water to infiltrate into soils. When runoff does occur, less sediment is carried along with it than when conventional plow-harrow tillage is used. Reduced tillage, by decreasing runoff and erosion, usually decreases both P and N losses from fields. Recent studies have also shown that reduced tillage results in more effective N cycling. Although N fertilizer needs are generally slightly higher in early transition years, long-term no-till increases organic matter contents over conventional tillage and also, after some years, results in 30 pounds (or more) per acre greater N mineralization, which is a significant economic benefit to the farm.
Reducing tillage usually leads to marked reductions of nitrate leaching loss to groundwater as well as to runoff and, therefore, N and P loss in runoff. But, questions have come up about potential problems with broadcasting N and P fertilizers in reduced tillage systems, especially in no-till. The main attractiveness of broadcast fertilizer is that you can travel faster and cover more land than with injection methods of application—around 500–800 acres in eight hours for broadcast versus about 200 acres for injection. However, there are two complicating factors.
- If intense storms occur soon after the application of surface-applied urea, N is more likely to be lost via leaching than if it had been incorporated. Much of the water will flow over the surface of no-till soils, picking up nitrate and urea, before entering wormholes and other channels. It then easily moves deep into the subsoil. It is best not to broadcast N fertilizer and to leave it on the surface with a no-till system. This is particularly true for urea, since surface residues contain higher levels of the urease enzyme, facilitating fast conversion to ammonia, which is rapidly lost as a gas. Fertilizer N may be applied at different stages: before planting, with the seed at planting, or as a sidedress. Using liquid N as a sidedress results in better soil contact than a solid fertilizer would achieve.
P accumulates on the surface of no-till soils (because there is no incorporation of broadcast fertilizers, manures, crop residues or cover crops). Although there is usually less runoff, fewer sediments and less total P lost with no-till, the concentration of dissolved P in the runoff is often higher than for conventionally tilled soils. Phosphorus should be applied below the surface to reduce such losses.
Working Toward Balancing Nutrient Imports and Exports
In addition to being contained in the products sold off the farm, nitrogen and phosphorus are lost from soils in many unintended ways, including runoff that takes both N and P, nitrate leaching (and in some situations, P as well), denitrification, and volatilization of ammonia from surface-applied urea and manures. Even if you take all precautions to reduce unnecessary losses, some N and P losses will occur. While you can easily overdo it with fertilizers, using more N and P than is needed also occurs on many livestock farms that import a significant proportion of their feeds. If a forage legume, such as alfalfa, is an important part of the rotation, the combination of biological N fixation plus imported N in feeds may exceed the farm’s needs. A reasonable goal for farms with a large net inflow of N and P through feed would be to try to reduce imports of these nutrients onto the farm (including legume N), or to increase exports, to a point closer to balance.
On crop farms, as well as on livestock-based farms with low numbers of animals per acre, it’s fairly easy to bring inflows and outflows into balance by properly crediting N from the previous crop, and N and P in manure. But it is a more challenging problem when there are a large number of animals for a fixed land base and a large percentage of the feed must be imported. This happens frequently in factory-type animal production facilities, but it can also happen on smaller, family-sized farms. At some point, thought needs to be given to either expanding the farm’s land base or exporting some of the manure to other farms. In the Netherlands, nutrient accumulation on livestock farms became a national problem and generated legislation that limits animal units on farms. One option is to compost the manure, which makes it easier to transport or sell. It causes some N losses during the composting process but stabilizes the remaining N before application. On the other hand, the availability of P in manure is not greatly affected by composting. That’s why using compost to supply a particular amount of “available” N usually results in applications of larger total amounts of P than plants need.
Using Organic Sources of Phosphorus and Potassium
Manures and other organic amendments are frequently applied to soils at rates estimated to satisfy a crop’s N need. This commonly adds more P and potassium than the crop needs. After many years of continuous application of these sources to meet N needs, soil test levels for P and potassium may be in the excessive range. Although there are a number of ways to deal with this issue, all solutions require reduced applications of fertilizer P and P-containing organic amendments. If it’s a farm-wide problem, some manure may need to be exported and N fertilizer or legumes relied on to provide N to grain crops. Sometimes, it’s just a question of better distribution of manure around the various fields: getting to those fields far from the barn more regularly. Changing the rotation to include crops such as alfalfa, for which no manure N is needed, can help. However, if you’re raising livestock on a limited land base, you should make arrangements to have the manure used on a neighboring farm or sell the manure to a composting facility.
Summary
Both N and P are needed by plants in large amounts, but when soils are too rich in these nutrients, they are environmental hazards. Although N and P behave somewhat differently in soils, most sound management practices for one are also sound for the other. Using soil tests, comprehensive nutrient management planning, and recommendation tools that account for all sources, such as soil organic matter, manures, cover crops, and decomposing sods, can help better manage these nutrients. Reduced tillage, cover crops, and rotation with sod crops decrease runoff and erosion and help in many other ways, including better N and P management. In addition, following the 4R-Plus principles and using technologies like N stabilizers/inhibitors as well as sensors and models can increase the use efficiency of N and P, and can reduce detrimental environmental impacts.