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10.2: Investigation - Cambrian Explosion and the Biogenous Rocks of Illinois

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    53320
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    The Cambrian Explosion some 540 million years ago marks the beginning of significant life forms on Earth. Illinois witnessed this landmark event in the warm topical sea. The rock history of Illinois tells the story. Before the Cambrian period, the sedimentary rocks in Illinois are lifeless sandstones. But starting with the middle of the Cambrian period and throughout the subsequent Ordovician and Silurian periods, Illinois rocks are flourished principally with calcite limestone and dolomite, up to over 5,000 feet in total rock thickness.

    Calcite limestone is an indicator of the presence of life in the sea. This rock is formed mainly from the hard parts of marine organisms, which had extracted calcium ions and carbonate ions from seawater to build shells, skeletons, and reefs. Unlike calcite, dolomite (magnesium calcium carbonate) is believed to be of non-biogenous in origin, and it does not easily form in laboratory environment either. This has led to the speculation that dolomite does not form directly but it evolved from calcite under geologic conditions through a process called dolomitization. One reason that magnesium calcium carbonate does not easily form is because of the small size of Mg2+ ion, as compared to the larger Ca2+ ion (Figure \(\PageIndex{1}\)). The dolomitization origin of dolomite implies that the dolomite found in early Paleozoic Illinois rocks were once calcite that formed from the shells and skeletons of marine species.

    Calcite model
    Figure \(\PageIndex{1}\): Molecular-scale model based on X-ray data shows that when a smaller ion (such as Mn2+) substitutes Ca2+ ion in CaCO3, the carbonate ion is forced to rotate in order for the O atom to reach outward to from the ionic bond. Unit = 0.1 nm. (Cheng, Sturchio, Bedzyk, Physical Review B, 2001; Copyright 2001 by American Physical Society.)
    Comparison between calcite and dolomite.
    Calcite Dolomite
    Chemical formula of mineral
    Radius of cation in mineral (in octahedral coordination)
    Name of rock containing the mineral
    Origin of mineral

    This page titled 10.2: Investigation - Cambrian Explosion and the Biogenous Rocks of Illinois is shared under a CC BY-NC-SA 4.0 license and was authored, remixed, and/or curated by Likwan Cheng.

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